The clean and mild synthesis,crystal structure,and intra-molecular hydrogen bond study of substituted new 4,8-dihydropyrano[3,2-b]-pyrans containing chlorokojic acid moiety

Research on Chemical Intermediates - A safe, green and convenient process was developed for the synthesis of a novel group of 4,8-dihydropyrano[3,2-b]-pyrans by dialkyl acetylenedicarboxylates and...     

The impact of the pitching motion on the structure of the vortical flow over a slender delta wing under sideslip angle

The primary purpose of this investigation is to observe the effect of the pitching motion on the vortical flow structure and bursting of leading-edge vortices over a delta wing under the sideslip angle, β using a dye visualization technique. In the current work, a delta wing with a sweep angle of Λ = 70° was oscillated in upstroke and downstroke direction to be able to discover the influence of pitching motion on the flow characteristics of the delta wing. The values of mean angles of attack were selected as α_m = 25° and α_m = 35°, and the sideslip angle was altered from β = 0 to 16°. The delta wing oscillated with the various periods of T_e = 5 s, 20 s, and 60 s, respectively. Amplitude of motion was adjusted as α_o =  ± 5°. It is found that the pitching motion of the delta wing under the sideslip angle β varies the location of the vortex bursting and vortical flow structure substantially.

     

An experimental study on optimization of $${\mathbf{SiO}}_{2}$$ SiO 2 /water nanofluid flows in circular minichannels

Journal of Thermal Analysis and Calorimetry - An experimental research was performed to examine the effect of hydrodynamically and thermally developing distilled water-based SiO $$_2$$ nanofluid...     

Study on the Inhibitory Activity of a Synthetic Defensin Derived from Barley Endosperm against Common Food Spoilage Yeast

In the food industry, food spoilage is a real issue that can lead to a significant amount of waste. Although current preservation techniques are being applied to reduce the occurrence of spoilage microorganisms, the problem persists. Food spoilage yeast are part of this dilemma, with common spoilers such as Zygosaccharomyces, Kluyveromyces, Debaryomyces and Saccharomyces frequently encountered. Antimicrobial peptides derived from plants have risen in popularity due to their ability to reduce spoilage. This study examines the potential application of a synthetic defensin peptide derived from barley endosperm. Its inhibitory effect against common spoilage yeasts, its mechanisms of action (membrane permeabilisation and overproduction of reactive oxygen species), and its stability in different conditions were characterised. The safety of the peptide was evaluated through a haemolysis and cytotoxicity assay, and no adverse effects were found. Both assays were performed to understand the effect of the peptide if it were to be consumed. Its ability to be degraded by a digestive enzyme was also examined for its safety. Finally, the peptide was successfully applied to different beverages and maintained the same inhibitory effects in apple juice as was observed in the antiyeast assays, providing further support for its application in food preservation.     

Better Optimization of Nonlinear Uncertain Systems (BONUS): A New Algorithm for Stochastic Programming Using Reweighting through Kernel Density Estimation

Given a series-parallel queueing network topology with exponential servers of finite capacity, a systematic design methodology is presented that approximately solves the optimal routing and buffer space allocation problems within the network. The multi-objective stochastic nonlinear programming problem in integer variables is described and a two-stage iterative optimization procedure is presented which interconnects the routing and buffer space allocation problems. The algorithmic procedure couples the Expansion method, a decomposition method for computing performance measures in queueing networks with finite capacity, along with Powell's unconstrained optimization procedure which allocates the buffers and a multi-variable search procedure for determining the routing probabilities. The effectiveness and efficiency of the resulting two-stage design methodology is tested and evaluated in a series of experimental designs along with simulations of the network topologies.     

A novel fully implicit finite volume method applied to the lid‐driven cavity problem—Part I: High Reynolds number flow calculations

A novel implicit cell‐vertex finite volume method is described for the solution of the Navier–Stokes equations at high Reynolds numbers. The key idea is the elimination of the pressure term from the momentum equation by multiplying the momentum equation with the unit normal vector to a control volume boundary and integrating thereafter around this boundary. The resulting equations are expressed solely in terms of the velocity components. Thus any difficulties with pressure or vorticity boundary conditions are circumvented and the number of primary variables that need to be determined equals the number of space dimensions. The method is applied to both the steady and unsteady two‐dimensional lid‐driven cavity problem at Reynolds numbers up to 10000. Results are compared with those in the literature and show excellent agreement. Copyright © 2003 John Wiley & Sons, Ltd.     

Creating a Low‐Potential Redox Polymer for Efficient Electroenzymatic CO2 Reduction

Increasing greenhouse gas emissions have resulted in greater motivation to find novel carbon dioxide (CO₂) reduction technologies, where the reduction of CO₂ to valuable chemical commodities is desirable. Molybdenum‐dependent formate dehydrogenase (Mo‐FDH) from Escherichia coli is a metalloenzyme that is able to interconvert formate and CO₂. We describe a low‐potential redox polymer, synthesized by a facile method, that contains cobaltocene (grafted to poly(allylamine), Cc‐PAA) to simultaneously mediate electrons to Mo‐FDH and immobilize Mo‐FDH at the surface of a carbon electrode. The resulting bioelectrode reduces CO₂ to formate with a high Faradaic efficiency of 99±5 % at a mild applied potential of ?0.66 V vs. SHE.     

Kinetic analysis of thermal decomposition of some Co-complexes of three unsymmetrical <Emphasis Type="Italic">vic</Emphasis>-dioximes ligands

The thermal decomposition of three new reagent cyclohexylamine-p-tolylglyoxime (L₁H₂), tertiarybutyl amine-p-tolylglyoxime (L₂H₂) and secondary butylamine-p-tolylglyoxime (L₃H₂ and their Co-complexes were studied by both isothermal and nonisothermal methods. As expected, the complex structure of Co-complexes, different steps with different activation energies were realized in decomposition process. Model-fitting and model-free kinetic approaches were applied to nonisothermal and isothermal data. The kinetic triplet (f(α), A and E) related to nonisothermal model-fitting method can not be meaningfully compared with values obtained from isothermal method. The complex nature of the multi-step process of the studied compounds was more easily revealed using a wider temperature range in nonisothermal isoconversional method.     

Microwave Assisted Synthesis of Chitosan Nanoparticles

Chitosan nanoparticles (CHN) were prepared based on ionotropic gelation between low moleculer weight chitosan and sodium tripolyphosphate (TPP) under microwave irradiation. Particle size, zeta potential, and FT-IR techniques were used for characterization of CHN. The influence of reaction time on the nanoparticle size distribution was investigated, and the results showed that the microwave irradiation method evidently decreases the reaction times and particle size over the conventional method. It was determined by the results of the zeta potential measurements that synthesized CHN under microwave irradiation clearly exhibits more homogeneous and stable dispersion.